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Authors: Lederer, Kay
Title: Crystalline assemblies of folded oligomers
Online publication date: 1-Jan-2000
Language: english
Abstract: In this work a novel design concept for folded oligomers is presented. The concept involves the insertion of a rigid spacer, the 1,3-bis(ethynylene)benzene unit, into linear alkyl-chain oligomers. Number and position of these spacers determine the molecular conformation of the oligomers in crystalline assemblies. In this way, chain folding is induced on crystallization at the air-water interface and in bulk. The packing arrangements in the crystalline monolayers were determined by grazing inzidence X-ray diffraction.
DDC: 540 Chemie
540 Chemistry and allied sciences
Institution: Johannes Gutenberg-Universität Mainz
Department: FB 09 Chemie, Pharmazie u. Geowissensch.
Place: Mainz
Version: Original work
Publication type: Dissertation
License: in Copyright
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Appears in collections:JGU-Publikationen

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